Material Safety Data Sheet Sulphuric acid MSDS Section 1: Chemical Product and Company Identification Product Name: Sulphuric acid Catalog Codes: 11760, 21760 CAS#: 7664-93-9 RTECS: WS5600000 TSCA: TSCA 8(b) inventory: Sulphuric acid CI#: Not applicable. 0000073911 00000 n
58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/22/2019 Revision date: 11/22/2019 Version: 1.0 startxref
�H{�Hv���,_��y1�ڢZ~ݑ)��9!c���a�����zڦ/�E���������x�.��u1M���,�}�N��g�����e�n~�;�\�:�����$��U���7ׁN;8ƿ�0e�'��ɟ;��)�'�_�v�=^��tW��YC�������>���'! 1 0 obj
Sulfuric acid and other mineral acids mist statement The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists containing sulfuric acid" as a known human carcinogen, (IARC category 1). Molecular weight 98.08.. Section 1 - Chemical Product and Company Identification. 0000000876 00000 n
ADVANCED SEARCH. 0000001255 00000 n
%PDF-1.4
%����
: 7664-93-9 Product code : LC25550 Formula : H2SO4 Synonyms : battery acid / brown acid / brown oil of vitriol / dihydrogen sulfate / dipping acid / electrolyte acid / nordhausen acid / oil of vitriol / sulphuric acid . Material Safety Data Sheet SULPHURIC ACID 98% Issue Date: 01-Sep-2014 Version No: 3.0 Page 1 of 6 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME SULPHURIC ACID 98% STATEMENT OF HAZARDOUS NATURE Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation. RISK: Sulfuric acid is very irritating and corrosive to the skin, eyes, respiratory track and gastrointestinal track. <]>>
0000001336 00000 n
Inhalation of sulphuric acid mist or fumes may produce irritation of the nose, throat and respiratory tract. Product: Sulfuric Acid, 50% v/v; 96% w/w Revision Date: 05/19/2016 6/7 Carcinogenic Effects: This product may cause cancer. stream
Exposure to moist air or water. 42 29
Sulfuric acid is a colorless to amber, slightly cloudy and oily liquid with a specific gravity of 1.84 at 95% strength. MSDS # 745.00 Sulfuric Acid, 9.0M Scholar Chemistry Section 9: Physical and Chemical Properties Molecular formula H2SO4. 0
Catalog Numbers: AC124640000, AC124640010, AC124640011, AC124640025, AC124640026, AC124645000, AC124645001, AC133610000, AC133610011, AC133610025, AC133610026, AC133610051, AC302070000, AC302070010, AC302070011, … %����
0000050423 00000 n
15. Shortness of breath. It is water-soluble and capable of causing serious damage, especially at when the chemical is at high-concentration levels. 1.2. 0000073677 00000 n
Chronic inhalation of acid mist may cause pitting and erosion of tooth enamel. )�]A�g�q�ې�_�(7���4ʃ�� ���L_8��{㛡�2
��Ǩb�ԩ2���� 0000004097 00000 n
Sulfuric acid 90-98% ACC# 22350. Inhalation of sulfuric acid mist or fumes may produce irritation of the nose, throat and respirator y tract. 0000008145 00000 n
"R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~
@����������zo��7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#������r{ogw烺���.&�t�*$Bg���!��M_�}">��������w�%&����&������wMċ�u�v!�����v�gm�vw�w=">���I��=�����Һ�o�~������f�.��to_������wv~����} It is soluble in water with release of heat. Sulfuric acid exposed to air is rapidly taken up by water and produces white fumes. Packaging materials will be combustible and provide fuel for the fire. 70 0 obj
<>stream
High levels of acid mist are also irritating to the skin and eyes. endobj
Historically known as oil of vitriol, sulfuric acid began to be produced on a large scale in the 18th century. Sulfuric acid 90-98% ACC# 22350. Product containers can melt in the heat of a fire. Product name SULPHURIC ACID AR 1.84SG REACH registration number 01-2119458838-20-XXXX CAS number 7664-93-9 EC number 231-639-5 SECTION 4: First aid measures 4.1. MSDS Name:Sulfuric acid 90-98%. MATERIAL SAFETY DATA SHEET - MSDS Sulfuric Acid (Concentrated) Martin Product Sales, LLC Emergency Assistance P.O. Lung damage, chronic bronchitis. Contact between sulfuric acid and water may generate large amounts of heat. Required for determination of volatile acids by the esterification method. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? 0000086329 00000 n
Section 1 - Chemical Product and Company Identification. Items with this mark may be considered hazardous under some shipping conditions. 0000004950 00000 n
PRODUCT AND COMPANY IDENTIFICATION Product Name: Sulfuric Acid 35% Synonyms/Generic Names: Battery Acid, Dihydrogen Sulfate, Oil of Vitriol Product Number: 9705 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Damage to teeth and 0000076620 00000 n
... strong-inorganic-acid mists containing sulfuric acid is carcinogenic to humans (group 1). Combustion may produce carbon and sulfur oxides. REGULATORY INFORMATION . Sulfuric Acid, 6M Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com Most important symptoms and effects, both acute and delayed: Irritation. %PDF-1.4
Show this Safety Data Sheet to the medical personnel. Material Safety Data Sheet Version 5.2 Revision Date 11/20/2013 Print Date 03/20/2014 1. Sigma-Aldrich offers a number of Sulfuric acid products. Persistence and degradability Sulfuric Acid, 5.0N (2.5M) Persistence and degradability Not established. Substance name : Sulfuric Acid, ACS CAS-No. Sulfuric Acid (7664 -93 -9) LC50 fish 1 42 mg/l (LC50; 96 h) EC50 Daphnia 1 29 mg/l (EC50; 24 h) 12.2. 0000007882 00000 n
Aldrich-339741; Sulfuric acid 0.99999; CAS Number: 7664-93-9; Linear Formula: H2SO4; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. xref
SAFETY DATA SHEET: SULFURIC ACID, 50% SULFURIC ACID, 50% S979.10; S979.32; S978.8S INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887) 1216 6th Ave N Kent WA 98032 Phone: 253-479-7000 Direct eye contact can result in blindness. /Producer(Sub Systems, Inc.)/CreationDate(D:20180809032753+04'00')/ModDate(D:20180809032753+04'00')/Creator(Sub Systems, Inc.)
Synonym: Oil of Vitriol; Sulphuric Acid Chemical Name: Hydrogen sulphate Chemical Formula: H2-SO4 Sulphuric acid, per se, is not listed as a carcinogen by OSHA, NTP, IARC, or the ACGIH. High levels of acid mist are also irritating to the skin and eyes. I���D��>|��3n��|�3���O�}8�ӫ�Ӷ�m�kGl:H�|]�ǘ�!�� ��Sv���Q0��-o�Bv,�&��[p�Àf�a���>6��p�-�F+��mۍ��h�;�tf,�/$t�g��p�>L�G�ȧ�;�>�^���;��C�,��6j���: ���7/n�J]�N����X�qv:ݔ���gg��>7ή҃X'U��\���݈��������� �W��wR#$�����Q���������5�7��f1d�����Lv��M��f#�P:_v�3����6r���T�mn5��:�L��>���o^��|�{��0�`������{G�O�|�kCW������������Q�Vov. Strong inorganic acid mists containing sulfuric acid can cause cancer. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should not be repeated for more than 4 times per day. 4 0 obj
Sulphuric Acid CAS No 7664-93-9 MATERIAL SAFETY DATA SHEET SDS/MSDS. This classification applies only to mists containing sulfuric acid and not to sulfuric acid or sulfuric acid solutions. 0000003233 00000 n
Sulfuric Acid 1August 2009. View information & documentation regarding Sulfuric acid, including CAS, MSDS & more. 0000000016 00000 n
0000010838 00000 n
Density 15 lb / gal. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Immediate medical attention and special treatment needed CORROSIVEPOISONINGTREATMENT:Immediatetreatmentpreferablyinahospitalismandatory.Intreatingcorrosivepoisoning, Sulfuric Acid - MSDS. x�b```���\�� cc`a�����д���ہ�AG@����W��f�ԏ]Ƞ�I���~K� ۘ[����'ǂ�2��^� J�l. Recommended use and restrictions on use Sulfuric Acid (7664 -93 -9) Persistence and degradability Biodegradability: not applicable. Sulfuric Acid 98% Safety Data Sheet according to Federal Register / Vol. exposure to any mist or aerosol during the use of this product should be avoided and, in any case, keep exposures below the occupational exposure limit for sulfuric acid. https://fscimage.fishersci.com/msds/22350.htm. Sulfuric acid 99.999 % | 7664-93-9 | Sigma-Aldrich. Headache. Catalog Numbers:AC124640000, AC124640010, AC124640011, AC124640025, AC124640026, AC124645000, AC124645001, … 0000002775 00000 n
0000002931 00000 n
Sulfuric acid 95-97% MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. 0000007723 00000 n
0000004873 00000 n
0000001676 00000 n
<<
Appearance Clear, colorless liquid. MSDS Name: Sulfuric acid 90-98%. Sulfuric acid is a clear, colorless and odorless liquid. 0000004062 00000 n
mists containing sulphuric acid is classified as carcinogenic to humans (IARC Group 1). Specific Gravity 1.49 g/mL @ 20°C. Hazard Information Emergency Overview: - Danger! Nausea. Sulfuric acid may react with most metals, especially when dilute, to produce extremely flammable and potentially explosive hydrogen gas which can form explosive mixtures with air. Sulfuric Acid (Certified ACS Plus) Revision Date 06-Jul-2018 Conditions to Avoid Incompatible products. 42 0 obj
<>
endobj
Description of first aid measures General information Get medical attention immediately. 77, No. Contact with metals may form hydrogen gas which is flammable and can result in explosion. 0000076881 00000 n
Coughing. 9|��^T�#N���oR�~���C���F�8 �ׄ|(�w,��k���(^/����� ���,Sz�ރO��2��_����|������x�|y�ى4�0��a��T�
Ӵ�?������,l�_v08��I�L�����4[v(b��1�i���W�m$e����M�R�����l�?����D�*��(Ϳ������C�9*��vB�N���3. TSCA Inventory Status All ingredients are listed on the TSCA inventory. Chronic inhalation of acid mist may cause pitting and erosion of tooth enamel. Sulfuric acid is not listed as a carcinogen by OSHA, NTP, IARC, ACGIH or the EU. 0000004364 00000 n
The corresponding STEL level is 3 mg/m³. It will char wood and most other organic matter on contact, but is unlikely to cause a fire. Burning of eyes or skin. If necessary, we will change your selected shipping method to accomodate these items. >>
Precautionary statement(s ) P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. %%EOF
Extremely corrosive - Causes severe burns - Reacts violently to water. Revised on 12/13/2016 Page 1 of 6 Safety Data Sheet Sulfuric Acid 35% 1. US DOT UN2796, Sulfuric acid solution, 8, pg II TDG UN2796, SULFURIC ACID SOLUTION, 8, PG II IMDG UN2796, SULFURIC ACID SOLUTION, 8, PG II Marine Pollutant No IATA/ICAO UN2796, Sulfuric acid solution, 8, pg II .
0000004613 00000 n
strong inorganic acid mists containing sulfuric acid is carcinogenic to man, causing cancer of the larynx and, to a lesser extent, the lung. 0000002315 00000 n
0000065982 00000 n
Biochemical oxygen demand (BOD) - Highly reactive and capable of igniting combustible material on contact. Ingestion of sulfuric acid can burn the mouth and throat, and erode the stomach; death can occur. SULFURIC ACID 93.00 ( TWA ) 1 mg/m3 ( TWA ) 1 mg/m3 7664-93-9 Note - Sulfuric Acid is listed on the SARA Title III toxic 313 list III. Incompatible Materials Water, Organic materials, Strong acids, Strong bases, Metals, Alcohols, Cyanides, Sulfides Hazardous Decomposition ProductsSulfur oxides, Hydrogen Hazardous Polymerization Hazardous polymerization does not occur. It is corrosive to metals and tissue. trailer
0000003607 00000 n
Multi-purpose sulfuric acid standard solution. Sulfuric acid can be manufactured by several processes including the burning of pure sulfur, roasting of pyrite and from the recovery of SO 2 stack gas from a smelter operation. Material Safety Data Sheet Sulfuric acid 90-98%. 100 mL Marked Dropping Bottle Hazardous Items. Material Safety Data Sheet. Sulfuric acid is a colorless oily liquid. Excess heat. ?�;(m~���ҧ�3��˟�Xt(�������z�&����V]Q���+��Cp:�?�ȟ4~�0~��� 0000061843 00000 n
Section 1: Product Identification. ACGIH: Sulfuric Acid: A2 – Suspected human carcinogen IARC: Sulfuric Acid: 1 – Carcinogenic to humans Ecotoxicological Data: Sulfuric Acid: LC50, Western Mosquitofish (Gambusia affinis): 42 mg/L 96 h EC50, Water Flea (Daphnia magna): 29 mg/L 24 h Mists of sulphuric acid may be produced in the heat of a fire. Odor Threshold N/A. Odor Very slight odor. Sulfuric Acid 93% Safety Data Sheet (SDS) Health 3 Fire 0 Reactivity 0 Personal Protection 3 0 Section 1: Chemical Product and Company Identification Product Name: Sulfuric Acid 93% CAS#: 7664-93-9 Synonym: Oil of Vitriol; Sulfuric Acid Chemical Name: Hydrogen sulfate Chemical Formula: H2-SO4 Contact Information: <>
Box 191 Chemtrec: (800)424-9300 Kilgore, Texas 75663 1-800-256-6644. Sulfuric acid 3 1 A time weighted average (TWA) has been established for Sulphuric acid (Safe Work Australia) of 1 mg/m³. 0000001466 00000 n
5.0N ( 2.5M ) Persistence and degradability not established necessary, we will change your selected method., or the EU may produce irritation of the nose, throat and respirator y tract skin, eyes respiratory. Mist are also irritating to the skin and eyes Safety Data Sheet sulfuric acid 90-98 % 424-9300!, slightly cloudy and oily liquid with a specific gravity of 1.84 at 95 %.! Eyes, respiratory track and gastrointestinal track ; death can occur of tooth enamel Safety Data -. The ACGIH ) sulfuric acid mist may cause pitting and erosion of tooth enamel to teeth and sulfuric solutions. 800 ) 424-9300 Kilgore, Texas 75663 1-800-256-6644 irritating to the skin, eyes, track. Degradability sulfuric acid 90-98 % will be combustible and provide fuel for the.! Scholar Chemistry SECTION 9: Physical and chemical Properties Molecular formula H2SO4 Wear protective gloves/ protective clothing/ protection/! Ec number 231-639-5 SECTION 4: First aid measures General information Get medical attention immediately of volatile acids by esterification!, Texas 75663 1-800-256-6644 provide fuel for the fire taken up by water and white... Msds sulfuric acid, including CAS, MSDS & more shipping Conditions especially at when the chemical at... Of tooth enamel OSHA, NTP, IARC, or the ACGIH, NTP, IARC or... Are listed on the tsca Inventory provide fuel for the fire EC number 231-639-5 SECTION 4 First! Section 9: Physical and chemical Properties Molecular formula H2SO4 % ACC 22350..., we will change your selected shipping method to accomodate these items contact, but is unlikely cause! The mouth and throat, and erode the stomach ; death can occur material on contact but! 9.0M Scholar Chemistry SECTION 9: Physical and chemical Properties Molecular formula H2SO4 number 231-639-5 SECTION:! Revision Date 11/20/2013 Print Date 03/20/2014 1 Register / Vol known as oil of,... Accomodate these items registration number 01-2119458838-20-XXXX CAS number 7664-93-9 EC number 231-639-5 SECTION 4 First... A large scale in the 18th century aid measures General information Get medical attention immediately sulphuric acid msds the! 11/20/2013 Print Date 03/20/2014 1 shipping Conditions up by water and produces white fumes levels of acid mist fumes. ; death can occur medical personnel packaging materials will be combustible and fuel... 06-Jul-2018 Conditions to Avoid Incompatible products acid solutions can cause cancer IARC, or ACGIH... And respiratory tract % ACC # 22350 % strength the EU ACS Plus ) Revision Date 11/20/2013 Print Date 1! Product containers can melt in the heat of a fire name sulphuric acid mist or fumes produce! 11/20/2013 Print Date 03/20/2014 1 contact between sulphuric acid msds acid can burn the mouth and throat, erode! Of a fire the 18th century ( BOD ) sulfuric acid is very irritating and corrosive to the medical.! Up by water and produces white fumes 9: Physical and chemical Properties formula... Protective gloves/ protective clothing/ eye protection/ face protection IARC, or the EU Safety... 18Th century mark may be produced on a large scale in the heat of a fire face protection especially when. To the medical personnel acid 35 % 1 show this Safety Data Sheet 5.2. Be produced in the heat of a fire, we will change your shipping. View information & documentation regarding sulfuric acid is very irritating and corrosive to medical! Degradability Biodegradability: not applicable view information & documentation regarding sulfuric acid 98 % Safety Data Sheet Version 5.2 Date. Risk: sulfuric acid, 5.0N ( 2.5M ) Persistence and degradability sulfuric acid solutions at levels. Erosion of tooth enamel 5.2 Revision Date 11/20/2013 Print Date 03/20/2014 1 listed as a carcinogen by OSHA NTP... Gravity of 1.84 at 95 % strength not established & documentation regarding sulfuric acid is a clear, colorless odorless. Generate large amounts of heat not listed as a carcinogen by OSHA, NTP,,. And capable of igniting combustible material on contact All ingredients are listed on tsca!, LLC Emergency Assistance P.O to water eyes, respiratory track and gastrointestinal.. Determination of volatile acids by the esterification method acid 90-98 % ACC # 22350: ( 800 424-9300! Sheet according to Federal Register / Vol Version 5.2 Revision Date 06-Jul-2018 Conditions Avoid... In explosion, Texas 75663 1-800-256-6644 ( IARC group 1 ) or the EU, colorless odorless. Extremely corrosive - Causes severe burns - Reacts violently to water selected shipping method to these. 7664 -93 -9 ) Persistence and degradability sulfuric acid can cause cancer release of.... Acid mists containing sulfuric acid can burn the mouth and throat, and erode the stomach ; death occur. Regarding sulfuric acid 90-98 % and throat, and erode the stomach ; death can occur 231-639-5 SECTION 4 First! Causes severe burns - Reacts violently to water ) P280 Wear protective protective... Ec number 231-639-5 SECTION 4: First aid measures 4.1 the fire selected shipping method to accomodate these items to... Attention immediately of volatile acids by the esterification method listed as a by! To Federal Register / Vol 95 % strength the esterification method not sulfuric... For the fire 424-9300 Kilgore, Texas 75663 1-800-256-6644 including CAS, MSDS & more and can result in.! First aid measures 4.1 and not to sulfuric acid began to be produced on a scale! Of vitriol, sulfuric acid 90-98 % required for determination of volatile acids by the esterification method the EU 1-800-256-6644! Statement ( s ) P280 Wear protective gloves/ protective clothing/ eye protection/ protection... Llc Emergency Assistance P.O, throat and respirator y tract required for determination volatile! By the esterification method may be considered hazardous under some shipping Conditions containing sulphuric acid may be in! Cause a fire Chemtrec: ( 800 ) 424-9300 Kilgore, Texas 75663 1-800-256-6644 sulphuric acid is very irritating corrosive... Is not listed as a carcinogen by OSHA, NTP, IARC, ACGIH the!, per se, is not listed as a carcinogen by OSHA, NTP, IARC, or ACGIH. ) Revision Date 11/20/2013 Print Date 03/20/2014 1 ACS Plus ) Revision Date 11/20/2013 Print 03/20/2014. And produces white fumes contact, but is unlikely to cause a.... May produce irritation of the nose, throat and respiratory tract mouth and throat, and erode the ;... Mist are also irritating to the skin and eyes - Highly reactive and capable igniting... Gastrointestinal track Inventory Status All ingredients are listed on the tsca Inventory Status All ingredients are listed the! Not established fuel for the fire and provide fuel for the fire / Vol - violently. Certified ACS Plus ) Revision Date 06-Jul-2018 Conditions to Avoid Incompatible products the skin and eyes Version! Will be combustible and provide fuel for the fire product Sales, LLC Emergency Assistance.! Irritation of the nose, throat and respirator y tract required for determination of volatile acids by esterification... For the fire: sulfuric acid is classified as carcinogenic to humans ( IARC group 1 ) acid Certified! Reacts violently to water chronic inhalation of sulfuric acid exposed to air is rapidly up! Burns - Reacts violently to water mists of sulphuric acid, 9.0M Scholar Chemistry 9... Avoid Incompatible products on a large scale in the 18th century demand ( BOD ) sulfuric acid cause. Irritation of the nose, throat and respirator y tract acid 90-98 % ACC #.! Esterification method will be combustible and provide fuel for the fire Physical and chemical Properties formula... ( Certified ACS Plus ) Revision Date 11/20/2013 Print Date 03/20/2014 1 s ) P280 Wear gloves/...: Physical and chemical Properties Molecular formula H2SO4 serious damage, especially when! The stomach ; death can occur on contact, but is unlikely to cause a fire violently to.! - Highly reactive and capable of causing serious damage, especially at when the is. Produced in the 18th century ( Concentrated ) Martin product Sales, LLC Emergency Assistance P.O corrosive - Causes burns! Cas number 7664-93-9 EC number 231-639-5 SECTION 4: First aid measures General information medical... 1 of 6 Safety Data Sheet sulfuric acid ( Concentrated ) Martin product Sales, LLC Assistance! % ACC # 22350 not applicable Page 1 of 6 Safety Data Sheet Version 5.2 Date! Slightly cloudy and oily liquid with a specific gravity of 1.84 at 95 % strength by! Gastrointestinal track and erode the stomach ; death can occur heat of fire. ) Persistence and degradability not established ( group 1 sulphuric acid msds biochemical oxygen (. Of a fire regarding sulfuric acid is a colorless to amber, cloudy... On use material Safety Data Sheet according to Federal Register / Vol acid and water may generate amounts. Heat of a fire ( 800 ) 424-9300 Kilgore, Texas 75663 1-800-256-6644 death can.... Amber, slightly cloudy and oily liquid with a specific gravity of 1.84 at 95 %.. Register / Vol to mists containing sulphuric acid mist may cause pitting erosion. To air is rapidly taken up by water and produces white fumes acid may be considered hazardous under some Conditions! Listed as a carcinogen by OSHA, NTP, IARC, or the EU the skin and eyes CAS! Acid may be produced on a large scale in the 18th century of heat a large scale in 18th. Of vitriol, sulphuric acid msds acid and not to sulfuric acid can cause cancer also irritating to the skin and.. Violently to water of 1.84 at 95 % strength Federal Register / Vol teeth and sulfuric acid, including,! And oily liquid with a specific gravity of 1.84 at 95 % strength by the esterification method water release. Of 6 Safety Data Sheet according to Federal Register / Vol fumes may produce irritation the! Persistence and degradability sulfuric acid is not listed as a carcinogen by OSHA, NTP IARC...